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- W2080811021 abstract "Efforts to develop catalysts for asymmetric hydrogenation using ruthenium(II)- chelated ditertiary phosphine complexes have led to the synthesis of the complexes [{Ru(PP)(CH3CN)}2μ-Cl3]+PF6−, [RuCl(PP)(CH3CN)3]+ PF6−, and [RuCl(η6- toluene)(PP)]+ PF6−, where PP=1,4-bis(diphenylphosphino)butane. The characterization of the complexes, including X-ray data for the pseudo-tetrahedral toluene complex, is described. In preliminary tests, the tris(acetonitrile) complex has been shown to be a precursor for a catalyst that effects homogeneous hydrogenation of terminal olefins, CH,CN, and imines." @default.
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- W2080811021 date "1985-11-01" @default.
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- W2080811021 title "Cationic ruthenium(II) complexes containing 1,4- bis(diphenylphosphino)butane and coordinated solvent molecules" @default.
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- W2080811021 doi "https://doi.org/10.1016/0022-328x(85)80342-9" @default.
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