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- W2080813956 abstract "Abstract The mesophase formation process of a main‐chain BB‐5(1‐Me) polyester in the supercooled isotropic‐liquid state has been studied using DSC, WAXD, and optical microscopy. The supercooled isotropic liquid follows two different SmCA formation processes. Above 85 °C, it forms the expected SmCA phase. Below, it yields a metastable SmA phase that displays a layer spacing almost twice the one of the SmCA phase. The SmA phase develops from a homogeneous nucleation followed by 3D growth and thereafter transforms to the SmCA phase. This two‐step SmCA formation involves a change in polymer chain configuration: first, the chains are folded in each two units to form the SmA phase and then they stretch to achieve the characteristic zigzag arrangement of the mesogens in the SmCA phase. magnified image" @default.
- W2080813956 created "2016-06-24" @default.
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- W2080813956 date "2010-11-15" @default.
- W2080813956 modified "2023-10-18" @default.
- W2080813956 title "Two-Step Smectic CA Phase Formation from Isotropic Liquid upon Supercooling in Main-Chain Liquid-Crystalline BB-5(1-Me) Polyester" @default.
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- W2080813956 doi "https://doi.org/10.1002/macp.201000398" @default.
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