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- W2080819903 abstract "An increased solubility of Nd3+ in YAG has been achieved by means of expansion of its crystal lattice with Sc3+ ions substituting for Al3+ ions in the octahedral sites. A number of other scandium substituted rare earth aluminum garnets of general formula {R3}[Sc2](Al3)O12 have been prepared and results are compared with similar compounds in {R3}[Sc2](Fe3)O12 systems. It is shown that the expansion of the YAG lattice by octahedral substitution significantly increases the solubility of Nd3+ on dodecahedral sites. The results of substitution of Sc in other rare earth-aluminum systems appear to be consistent with results obtained in the yttrium-aluminum system and so ions bigger than Gd3+, such as Eu3+ and Sm3+, can form garnets {Eu3}[Sc2](Al3)O12 and {Sm3}[Sc2](Al3)O12." @default.
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- W2080819903 date "1973-09-01" @default.
- W2080819903 modified "2023-10-16" @default.
- W2080819903 title "Solubility enhancement of Nd7+ in scandium-substituted rare earth-aluminum garnets" @default.
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- W2080819903 doi "https://doi.org/10.1016/0022-4596(73)90018-2" @default.
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