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- W2080841405 abstract "A study was made of interaction between oligomer polyethylene glycols of molecular weights 300, 600, 1500, 3000, 6000 and 20,000 and transition metal compounds (MeCln; TiCl4, ZrCl4, VCl4, VOCl3 and NbCl5). The formation of metal esters as a result of hydroxyl end groups of polyethylene glycols is the first stage of interaction in these systems. With excess MeCln complexes are formed and the MeCln molecule is added to the fragment consisting of three oxy-ethylene. It was established that the frequency of stretching vibrations of COC bonds undergoes a bathochromic shift in IR spectra during complex formation by 50-17 cm−1, according to the type of MeCln. Assumptions were expressed concerning the structure of these oligomer complexes. Degradation takes place in polyethylene glycols during interaction with MeCln, the degree of those processes depending on chain length and the type of polyethylene glycol." @default.
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- W2080841405 date "1981-01-01" @default.
- W2080841405 modified "2023-09-23" @default.
- W2080841405 title "Study of complex-formation between polyethylene glycols and transition metal halides" @default.
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- W2080841405 doi "https://doi.org/10.1016/0032-3950(81)90319-1" @default.
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