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- W2080841738 abstract "Abstract 2-Allyloxyphenylcarbenes ( 8 ) undergo intramolecular addition (→ 9 ) and (formal) CH insertion (→ 11 ) competitively. Stereochemical labels indicate that 11 and major amounts of 9 arise from triplet 8 . The intermolecular OH insertion of singlet 8 with methanol (neat) is ca. 50 times faster than intramolecular addition. Under these conditions, intramolecular reactions and intersystem crossing of triplet 8 proceed at similar rates ( k T ∼ k TS )." @default.
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- W2080841738 date "1997-02-01" @default.
- W2080841738 modified "2023-09-26" @default.
- W2080841738 title "Intramolecular reactivity of functionalized arylcarbenes: 2-allyloxyphenylcarbenes" @default.
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- W2080841738 doi "https://doi.org/10.1016/s0040-4039(97)00090-7" @default.
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