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- W2080867589 abstract "Benson's isodesmic reactions (1965) for the description of relative stabilities of free radicals have been systematically used for choosing or correcting the quoted values of the enthalpies of formation of some free radicals. Isodesmic reactions are further used for quantification of structure–stability relationship for free radicals from which new quantitative regularities are derived. In many examples it was demonstrated that these regularities could form a basis for a general methodology of estimation of the enthalpies of formation for free radicals of any structure which sometimes serves as an alternative to experiment. Special cases of alkyl and PhX (X=CH2, NH, O) free radicals are considered in detail, demonstrating the utility of the application of isodesmic reactions to thermochemistry of free radicals." @default.
- W2080867589 created "2016-06-24" @default.
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- W2080867589 date "1997-12-01" @default.
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- W2080867589 title "Some regularities in the relative thermodynamic stabilities of free radicals" @default.
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- W2080867589 doi "https://doi.org/10.1016/s0022-2860(97)00198-1" @default.
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