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- W2080876895 abstract "Magic-angle sample-spinning NMR spectra of $^{111}mathrm{Cd}$ and $^{125}mathrm{Te}$ in ${mathrm{Cd}}_{1mathrm{ensuremath{-}}mathrm{x}}$${mathrm{Zn}}_{mathrm{x}}$Te semiconductor alloys have been recorded for 0ensuremath{le}xensuremath{le}1. The $^{111}mathrm{Cd}$ NMR spectra exhibit a single line whose chemical shift and linewidth depend on x. The linear dependence of the $^{111}mathrm{Cd}$ chemical shift on x is assumed to be the result of charge transfer, while the linewidth dependence is shown to be the result of a random distribution of Zn atoms which are next-nearest neighbors to Cd. The $^{125}mathrm{Te}$ spectra exhibit multiple lines, their number and chemical shift depending on x. The different chemical shifts of the Te lines are assigned to the five different cation configurations---${mathrm{Cd}}_{mathrm{n}}$${mathrm{Zn}}_{4mathrm{ensuremath{-}}mathrm{n}}$, n=0,...,4---around the Te. The intensities of the experimental Te lines are compared to those in spectral simulations obtained by assuming a random distribution of the cations. The comparison reveals small deviations from a random distribution of the cations. This clustering phenomenon and the effect of the bond-length changes with x on the $^{125}mathrm{Te}$ chemical shift are discussed." @default.
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- W2080876895 date "1987-10-15" @default.
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- W2080876895 title "Te and Cd nuclear-magnetic-resonance study of local structure and bonding in<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>Cd</mml:mi></mml:mrow><mml:mrow><mml:mn>1</mml:mn><mml:mi mathvariant=normal>−</mml:mi><mml:mi mathvariant=normal>x</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi …" @default.
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- W2080876895 doi "https://doi.org/10.1103/physrevb.36.6420" @default.
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