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- W2080881867 abstract "Abstract The formation characteristics of hydroxide films on aluminum were studied at 99.5 °C in neutral solutions of citrate, silicate, and phosphate (10 −4 – 10 −2 M) as well as in doubly distilled water(DDW), by gravimetry, chemical analysis, TEM, and XPS. In silicate and phosphate solutions both the oxidation of aluminum and formation of hydroxide films are retarded with increasing anion concentration, and in citrate solutions the oxidation rate increases but the film formation rate decreases. TEM showed that all the films formed in the test solutions consist of one layer except with DDW and 10 −4 M silicate solution, and the thickness decreased with increasing anion concentration. The film formed in DDW and 10 −4 M silicate solution had a two layered structure. According to XPS, appreciable amounts of silicate or phosphate were included in the film formed in all solutions. The role of the anions on hydration of aluminum is discussed in terms of the stability and dissolution of surface films." @default.
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- W2080881867 title "The role of anions in the formation of hydroxide films on aluminum in hot aqueous solutions" @default.
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- W2080881867 doi "https://doi.org/10.1016/0010-938x(90)90114-k" @default.
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