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- W2080883690 abstract "Abstract The reaction of silver(I) with 1,2-bis[1-(pyridin-2-yl)ethylidene]hydrazine (bpeh) and N,N-bis(pyridin-2-ylmethyl)amine (bpma) in the presence of Na(sac) (sac = saccharinate) yielded [Ag2(sac)2(bpeh)] (1) and [Ag(sac)(bpma)]n (2) with conformational chirality. Both complexes have been characterized by elemental analysis, IR, thermal analysis and X-ray single crystal diffraction. Complex 1 displays a binuclear composition, in which each silver(I) ion is bound to one monodentate sac ligand and one of the bidentate pyridylimino groups of the bpeh ligand in a distorted trigonal coordination geometry. Complex 2 is a one-dimensional helical polymer, in which silver(I) centers are bridged by tridentate bpma ligands, and each silver(I) ion is coordinated in a distorted tetrahedral geometry by one monodentate sac ligand, a bidentate pyridylamine group of one bpma ligand, and a py group of another bpma ligand. Weak intermolecular C–H⋯O hydrogen bonds and C–H⋯π interactions lead to assembly of 1 and 2 into three-dimensional supramolecular frameworks. Spectral and thermal analysis data for 1 and 2 are in agreement with the crystal structures. In addition, both complexes in the solid state display intraligand π–π∗ fluorescence." @default.
- W2080883690 created "2016-06-24" @default.
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- W2080883690 date "2010-03-01" @default.
- W2080883690 modified "2023-09-22" @default.
- W2080883690 title "Dimeric and polymeric silver(I) saccharinato complexes of two bis(pyridine) ligands: Synthesis, structural, spectroscopic, fluorescent and thermal properties" @default.
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- W2080883690 doi "https://doi.org/10.1016/j.poly.2010.01.019" @default.
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