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- W2080887464 startingPage "1257" @default.
- W2080887464 abstract "The irradiation of a mixture of diphenylacetylene (I) and the enamine of the diethyl ketone (II) or of cyclopentanone (IV) gives two β,γ-unsaturated ketones, III and X respectively, in which the diphenylacetylene moiety is formally inserted into the respective enamine double bond under hydrogen migration. The reaction with the enamine of cyclohexanone (V) affords 2-(1,2-diphenylvinyl)cyclohexanone (XIII) as the major product in addition to the cycloadduct (XV). In each case, the formation of photodimers of I has been observed. The reaction is quenched by the addition of pyrene, is sensitized by triphenylene, and is supposed to proceed by way of a triplet path. The different routes of the enamine reactions can be explained by considering the geometry of the intermediate diradicals." @default.
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- W2080887464 date "1973-04-01" @default.
- W2080887464 modified "2023-09-26" @default.
- W2080887464 title "The Photochemical Reaction of Diphenylacetylene with Enamines" @default.
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- W2080887464 doi "https://doi.org/10.1246/bcsj.46.1257" @default.
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