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• W2080891190 abstract "In the presence of Pd(OAc) 2 and norbornene as catalysts, two molecules of an ortho-substituted aryl iodide undergo aryl–aryl coupling to a palladium-bonded biphenylyl intermediate, which is hydrogenolyzed by benzyl alcohol to give 2,3′-disubstituted biaryl derivatives in satisfactory yields. A curious behaviour was observed with o-chloroiodobenzene, which gave activation of the C—Cl bond with four-membered ring formation.Key words: biphenyls, aryl–aryl coupling, multistep reactions, palladium, palladacycles, C-H activation, catalysis." @default.
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• W2080891190 date "2005-06-01" @default.
• W2080891190 modified "2023-10-11" @default.
• W2080891190 title "Palladium-catalysed synthesis of nonsymmetrically disubstituted-1,1′-biphenyls from <i>o</i>-substituted aryl iodides through aryl coupling and delayed hydrogenolysis" @default.
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• W2080891190 doi "https://doi.org/10.1139/v05-084" @default.
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