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- W2080919804 abstract "The stability of nanosized materials differs significantly from the stability of bulk materials. In this study a thermodynamic analysis on the simultaneous oxidation and re-reduction of small metallic cobalt crystallites in the presence of water and hydrogen as a function of the crystallite diameter was performed as a model for catalyst deactivation in the Fischer−Tropsch synthesis. It is shown that spherical cobalt crystallites with a diameter less than 4.4 nm are likely to be oxidized under realistic Fischer−Tropsch synthesis conditions (pH2O/pH2 < 1.5, T = 493 K)." @default.
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- W2080919804 date "2005-01-27" @default.
- W2080919804 modified "2023-10-18" @default.
- W2080919804 title "Stability of Nanocrystals: Thermodynamic Analysis of Oxidation and Re-reduction of Cobalt in Water/Hydrogen Mixtures" @default.
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- W2080919804 doi "https://doi.org/10.1021/jp045136o" @default.
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