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• W2080943695 startingPage "13470" @default.
• W2080943695 abstract "Oxidation of tin nanoparticles is studied in this paper using a simultaneous TGA/DSC technique under both constant rates of heating and isothermal modes. A two-stage oxidation process is identified. XRD study shows that the only oxide product is SnO at a temperature below 400 °C, and SnO and SnO2 coexist at the temperature range between 400 and 900 °C. On the basis of the identified oxide constituent, the first-stage oxidation of tin nanoparticles is investigated by the model-free Kinssinger method. The activation energy is found to be dependent on the conversion ratio in a broad range of 0.32−1.33 eV, and the oxidation kinetics is identified to be the classical nucleation mechanism that can be modeled by the Avrami−Erofeev equation. The melting of tin and large pressure built up in a rigid oxide shell are believed to be responsible for the heterogeneous nucleation mechanism." @default.
• W2080943695 created "2016-06-24" @default.
• W2080943695 creator A5055809196 @default.
• W2080943695 creator A5070857673 @default.
• W2080943695 date "2009-07-13" @default.
• W2080943695 modified "2023-10-03" @default.
• W2080943695 title "Experimental Investigation of the Oxidation of Tin Nanoparticles" @default.
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• W2080943695 doi "https://doi.org/10.1021/jp902580s" @default.
• W2080943695 hasPublicationYear "2009" @default.
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