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- W2080948804 abstract "In order to test experimentally the reaction pathways postulated from previous experimental and theoretical investigations, the following studies were carried out. An investigation into the effect of pressure and O2 on the OH Meinel band emission from the reaction of O3 with simple olefins. An extension of previous studies of chemiluminescence from low pressure gas phase ozone reactions to the following classes of compounds: cyclic olefins (cyclopentene), alkynes (acetylene), diolefins (allene, 1,3-butadiene) and unsaturated aldehydes (acrolein and crotonaldehyde). These compounds provide possibilities for diversion of the normal reaction paths not present in simple olefins. In order to test the mechanisms proposed in the literature to account for chemiluminescent species studies were carried out on the following selected organic compounds to determine whether the chemiluminescence observed was predicted by the mechanistic theories: 3-methyl-1-butene to attempt to determine the mechanistic pathway for the production of glyoxal phosphorescence; 1,1- and 1,2-difluoroethylene, 3,3,3-trifluoropropylene, 1,1-dichloropropylene, cyclopentene, acrolein, trans-3-hexene and trans-4-octene to investigate the pathways for production of formaldehyde fluorescence; a series of deuterated and partially deuterated propylenes for the production of OH Meinel band emission. The data and chemiluminescent spectra obtained are reported, leading to the conclusion that the present theories of ozone—olefin reactions do not entirely predict the chemiluminescing species observed. Furthermore, it appears that the overall mechanism for production of vibrationally excited hydroxyl radicals from ozone—olefin reactions is so complex that a satisfactory mechanism cannot easily be deduced by simply studying the effect of variable reactant concentrations and total pressure." @default.
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- W2080948804 date "1977-01-01" @default.
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- W2080948804 title "Structural effects on the chemiluminescence from the reaction of ozone with selected organic compounds" @default.
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- W2080948804 doi "https://doi.org/10.1016/0047-2670(77)80021-x" @default.
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