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- W2080962627 abstract "The synthesis of ABA triblock copolymers comprised of polyisobutylene (PIB) and poly(γ-benzyl-l-glutamate) (PBLG) segments has been demonstrated for the first time by the polymerization of γ-benzyl-l-glutamate N-carboxyanhydride (BLG-NCA) initiated with well-defined α,ω-primary amino-functional PIBs. The ammonium-mediated polymerization of BLG-NCA provided better control of molecular weights and lower polydispersity indices (PDIs) compared to the conventional polymerization. The compositional homogeneity of the block copolymers has been confirmed by GPC-MALLS and 1H NMR spectroscopy. Since the resulting ABA triblock copolymer possessed primary amino groups at α,ω-ends, further extension reaction with 4,4′-methylene-bis(phenyldiisocyanate) was possible to afford a novel (ABA)n multiblock copolymer." @default.
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- W2080962627 date "2009-07-01" @default.
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- W2080962627 title "Synthesis of novel ABA triblock and (ABA) multiblock copolymers comprised of polyisobutylene and poly(γ-benzyl-l-glutamate) segments" @default.
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- W2080962627 doi "https://doi.org/10.1016/j.reactfunctpolym.2008.12.002" @default.
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