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• W2080981670 startingPage "6152" @default.
• W2080981670 abstract "The reaction of [RuCl2(PPh3)3] with K[H2B(pz)2] (pz = pyrazol-1-yl) in tetrahydrofuran at room temperature provides the known hydrotris(pyrazolyl)borate complex [RuH(PPh3)2{HB(pz)3}] (1b) via pyrazole scrambling. In contrast, the reaction of [RuCl2(PPh3)3] with K[H2B(pz)2] in methanol does not, as previously reported, provide [Ru(PPh3)2{H2B(pz)2}2] but, rather, a mixture of the complexes [RuX(PPh3)2{κ3O,N,N′-(MeO)2B(pz)2}] (X = H (2a), Cl (2b)) and ttt-[RuCl2(Hpz)2(PPh3)2] (3), each of which have been structurally characterized. Although the resulting bulk admixtures of 2a,b have so far proved inseparable, treatment with mercuric chloride cleanly converts the 2a component to 2b. Heating 2b with 1,2-bis(dicyclohexylphosphino)ethane (dcpe) results in substitution of both phosphine ligands and the formation of [RuCl(dcpe){κ3O,N,N′-(MeO)2B(pz)2}] (4) in which the ruthenium−ether linkage is ultimately retained." @default.
• W2080981670 created "2016-06-24" @default.
• W2080981670 creator A5018038109 @default.
• W2080981670 creator A5031807767 @default.
• W2080981670 creator A5066870453 @default.
• W2080981670 creator A5091826237 @default.
• W2080981670 date "2009-10-12" @default.
• W2080981670 modified "2023-09-24" @default.
• W2080981670 title "Boron Functionalization of Bis(pyrazolyl)borate Ligands: Molecular Structures of [RuX(PPh₃)₂{(MeO)₂B(pz)₂}] (X = H, Cl; pz = pyrazol-1-yl)" @default.
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• W2080981670 doi "https://doi.org/10.1021/om9006592" @default.
• W2080981670 hasPublicationYear "2009" @default.
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