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- W2080985599 abstract "Rhodium(I) complexes [Rh(TropNMe)(CO)(PPh3)] (TropNMe = 2-(N-methylamino)tropone, ONC8H9) (1) and [Rh(Trop)(CO)(PPh3)] · Acetone (Trop = Tropolone, O2C7H6) (2) have been synthesized and characterized by single-crystal X-ray diffraction analysis. A distorted square planar geometry about the rhodium(I) metal centre is observed in both compounds 1 and 2. Substitution of an oxygen atom with a methyl functionalized nitrogen atom does not significantly alter the bond distances and angles in the rhodium(I) complex. A theoretical study at B3LYP/6-31G(d) (main group) and LANL2DZ (Rh) level is presented to clarify the solid state behaviour of these complexes." @default.
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- W2080985599 date "2007-11-01" @default.
- W2080985599 modified "2023-10-16" @default.
- W2080985599 title "Synthesis, structure and theoretical study of two rhodium(I) complexes [Rh(TropNMe)(CO)(PPh3)] and [Rh(Trop)(CO)(PPh3)]·Acetone" @default.
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- W2080985599 doi "https://doi.org/10.1016/j.poly.2007.07.039" @default.
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