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• W2081001034 abstract "Abstract The structure of InMO 3 (ZnO) m (M = In, Fe, Ga, and Al; m = integer) is built from InO 2 1− (In–O) and MZn m ,O m +1 1 m (M/Zn–O) layers stacked alternately. A modulated structure of these compounds results from the ordering of M ions in the M/Zn–O layers. The modulated structures of InMO 3 (ZnO) 13 (M = In 0.5 A 0.5 ; A = Fe, Ga, and Al), a solid solution of InInO 3 (ZnO) 13 and InMO 3 (ZnO) 13 (M =Fe, Ga, and Al), have been studied by high-resolution electron microscopy. The main and satellite spots of the electron diffraction patterns are indexed as ha * + kb * + lc * + mq by using the four dimensional superspace group approach. Based on the crystal system of the basic structure and the modulation wave vector q , the electron diffraction patterns are classified according to three categories with typical parameters: (1) monoclinic unit cell of a = 0.57 nm, b = 0.33 nm, c = 4.0 nm, β = 93° and q = b */18.1; (2) monoclinic unit cell of a = 0.57 nm, b = 0.33 nm, c = 4.0 nm, β = 93°, and q = b */22.5 + c */2; (3) triclinic unit cell of a = 0.57 nm, b = 0.33 nm, c = 4.0 nm, α = 95°, β = 95°, γ = 30°, and q = a */12.1 + b */18.1 + c */32.3. Among these, the first is the same as that of their constituent compounds In 2 O 3 (ZnO) 13 and InMO 3 (ZnO) 13 (M = Fe, and Ga), while the second and the third are different. In high-resolution image, the modulated structure appears as zig-zag contrast within the M/Zn–O layers. The periodicity of this zig-zag contrast along the M/Zn–O layer in InMO 3 (ZnO) 13 (M = In 0.5 A 0.5 ; A = Fe, Ga, and Al) is between those of InInO 3 (ZnO) 13 and InMO 3 (ZnO) 13 (M = Fe, Ga, and Al)." @default.
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• W2081001034 date "1999-09-01" @default.
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• W2081001034 title "High-resolution electron microscopy of a modulated structure in InMO₃(ZnO)_<i>m</i> (M = In, Fe, Ga, and Al; <i>m</i> = integer): effect of solid solution formation" @default.
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• W2081001034 doi "https://doi.org/10.1524/zkri.1999.214.9.528" @default.
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