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• W2081021645 abstract "Treating fluorenone or 2-benzoylpyridine with the sodium zincate [(TMEDA)·Na(μ-tBu)(μ-TMP)Zn(tBu)] in hexane solution, gives efficient tBu addition across the respective organic substrate in a highly unusual 1,6-fashion, producing isolable organometallic intermediates which can be quenched and aerobically oxidised to give 3-tert-butyl-9H-fluoren-9-one and 2-benzoyl-5-tert-butylpyridine respectively." @default.
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• W2081021645 date "2011-01-01" @default.
• W2081021645 modified "2023-09-26" @default.
• W2081021645 title "Remote functionalisation via sodium alkylamidozincate intermediates: access to unusual fluorenone and pyridyl ketone reactivity patterns" @default.
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• W2081021645 doi "https://doi.org/10.1039/c1cc10193e" @default.
• W2081021645 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21350770" @default.
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