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- W2081025475 abstract "Molybdenum oxomethoxide and ethoxide are found to react very rapidly with aldehydes and ketones in both alcohol and hydrocarbon media transforming the latter into acetals and ketals respectively. The colloid solution of the molybdenum blue usually formulated as “MoO2.88·H2O” appears to be the major inorganic product of this reaction. The reaction mechanism includes presumably formation of a semiacetal molybdate and its subsequent decomposition with elimination of acetal. Different reaction pathways of metal alkoxides interaction with aldehydes and ketones are discussed." @default.
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- W2081025475 date "1998-01-01" @default.
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- W2081025475 title "A new argument in favor of the ether elimination mechanism: formation of acetals on action of molybdenum alkoxides on carbonyl compounds" @default.
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- W2081025475 doi "https://doi.org/10.1016/s0277-5387(98)80006-5" @default.
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