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- W2081036315 endingPage "4833" @default.
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- W2081036315 abstract "Diblock copolymers, which are heterogeneous in both molar mass and composition, can be fully characterized by using two-dimensional chromatography. Since the size-exclusion, the adsorption, and the critical interaction based modes of chromatography are possible for each of the polymers A and B, this leads to a variety of options for 2D-chromatography of copolymers AB. Using the theory of chromatography of block copolymers, 2D-chromatograms are simulated that correspond to the most interesting of these options. Orthogonal 2D-chromatograms are expected, if in the 1st dimension the critical condition is created for A, while in the 2nd dimension--for B. The situations, where A and B are both adsorbable, as well as those where the conditions of adsorption for A and SEC for B are created, are also considered. In particular, it is shown that the 2nd dimension combination of the critical condition for A and SEC--for B is preferable than that with SEC condition for both A and B. The simulated 2D-chromatograms of low- and high molar mass diblock copolymers, as well as of copolymers with one short block are compared with the reported real ones; it is concluded that the corresponding virtual and real 2D-chromatograms are qualitatively very similar." @default.
- W2081036315 created "2016-06-24" @default.
- W2081036315 creator A5002435770 @default.
- W2081036315 creator A5064120772 @default.
- W2081036315 date "2010-07-01" @default.
- W2081036315 modified "2023-10-12" @default.
- W2081036315 title "Two-dimensional liquid chromatography of diblock copolymers: Simulation at various adsorption interaction conditions" @default.
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- W2081036315 doi "https://doi.org/10.1016/j.chroma.2010.05.045" @default.
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