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- W2081107079 abstract "Ozonations of ammonia, amines, anilines, and p-phenylenediamines have been shown to proceed via an electron transfer reaction mechanism. The ozonation rate constants for the alkenes with different substituents were shown to be linearly correlated with the ionization potentials of the corresponding olefinic substrates. The rate constants for the ozonations of methyl-substituted benzenes were also shown to be linearly correlated with the ionization potentials of the corresponding aromatic substrates. These results together with other related experimental evidences lead us to suggest that the olefinic ozonations proceed via an electron transfer reaction mechanism (Scheme 4). This mechanism explains why the derivatives of p-phenylenediamine can be used as efficient antiozonants to prevent the degradation of rubber products caused by ozone." @default.
- W2081107079 created "2016-06-24" @default.
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- W2081107079 date "1997-08-01" @default.
- W2081107079 modified "2023-10-16" @default.
- W2081107079 title "Olefinic Ozonation Electron Transfer Mechanism" @default.
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- W2081107079 doi "https://doi.org/10.1021/jo970297s" @default.
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