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- W2081119141 startingPage "617" @default.
- W2081119141 abstract "A calculation based on Longuet-Higgins and Murrell’s method using the MO’s of aniline and phenol obtained by the SCF-MO-CI calculation is carried out for the π-electron structures of (−)-6,6′-diamino-(I) and (−)-6,6′-dihydroxy-bis-1,1′-spiroindane (II). These wave functions are then used to calculate the rotation strengths of these compounds. The circular dichroism curves calculated from the results, assuming a Gaussian curve, are compared with the observed spectra; a quantitative agreement with the experimental value is found. The nature of the transitions and the origin of the optical activity are also discussed." @default.
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- W2081119141 date "1971-03-01" @default.
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- W2081119141 title "The Optical Activity of Bis-1,1′-spiroindanes. The Direct Calculation of Optical Rotational Strengths" @default.
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- W2081119141 doi "https://doi.org/10.1246/bcsj.44.617" @default.
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