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- W2081127048 abstract "The γ-radiolysis of a series of blends of bisphenol-A polycarbonate and poly(bisphenol-A-co-phthalate) with poly(3-hydroxybutyrate-co-3-valerate) has been investigated at 77 K. The ESR spectra of the radicals formed on radiolysis have been delineated and compared with the spectra which would be expected for a linear additive model. This comparison showed that these was a greater contribution to the spectrum from the aromatic polyesters than from the aliphatic polyester. However, the radiation chemical yields for radical formation were found to adhere closely to the predictions of the linear additive model. This latter observation suggests that the blends are not miscible at the level required for effective radiation protection of the aliphatic polyester which has a much higher sensitivity to radiation damage. Thermal analyses of the blends showed two glass transition temperatures at those of the homopolymer components, typical of the behaviour of a phase-separated system, but there was also evidence of a modified crystalline structure in the aliphatic polyester through a depression of the melting temperature in the blends. © 1999 Society of Chemical Industry" @default.
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- W2081127048 date "1999-10-01" @default.
- W2081127048 modified "2023-10-14" @default.
- W2081127048 title "Radiation chemistry of arylpolyester blends with a polyalkanoate" @default.
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- W2081127048 doi "https://doi.org/10.1002/(sici)1097-0126(199910)48:10<963::aid-pi255>3.0.co;2-k" @default.
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