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• W2081134765 abstract "A quantitative study of polaron and bipolaron formation in polypyrrole upon electrochemical doping is presented. The steady-state spin concentration has been measured as a function of the electrical potential in an in situ ESR-electrochemical experiment and the charge injection has been determined by coulometry and by optics. The data are analysed from both physical and electrochemical points of view. It is shown that the energy for creating a bipolaron is about the same as for creating two polarons. The non-Nernstian behaviour that is observed for the redox process is explained by the introduction of interparticle charge repulsion interactions. The shape of these interactions is specified." @default.
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• W2081134765 date "1986-06-01" @default.
• W2081134765 modified "2023-10-16" @default.
• W2081134765 title "Polarons, bipolarons and charge interactions in polypyrrole: Physical and electrochemical approaches" @default.
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• W2081134765 doi "https://doi.org/10.1016/0379-6779(86)90143-8" @default.
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