FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2081214922> ?p ?o ?g. }

• W2081214922 endingPage "8545" @default.
• W2081214922 startingPage "8537" @default.
• W2081214922 abstract "Amorphous ABA type block aliphatic polyesters can be useful as degradable and biorenewable thermoplastic elastomers. These materials can be prepared by sequential ring-opening transesterification polymerization (ROTEP) reactions and can exhibit a range of physical properties and morphologies. In this work a set of amorphous polylactide–poly(6-methyl-ε-caprolactone)–polylactide aliphatic polyester ABA triblock copolymers were prepared by consecutive controlled ring-opening polymerizations. Ring-opening polymerization of neat 6-methyl-ε-caprolactone in the presence of 1,4-benzenedimethanol and tin(II) octoate afforded α,ω-hydroxyl-terminated poly(6-methyl-ε-caprolactone). High conversions of 6-methyl-ε-caprolactone (>96%) afforded polymers with molar masses ranging from 12 to 98 kg mol–1, depending on monomer-to-initiator ratios, polymers with narrow, monomodal molecular weight distributions. An array of polylactide–poly(6-methyl-ε-caprolactone)–polylactide triblock copolymers with controlled molecular weights and narrow molecular weight distributions were synthesized using the telechelic poly(6-methyl-ε-caprolactone) samples as macroinitiators for the ring-opening polymerization of d,l-lactide. The morphological, thermal, and mechanical behaviors of these materials were explored. Several triblocks adopted well-ordered microphase-separated morphologies, and both hexagonally packed cylindrical and lamellar structures were observed. The Flory–Huggins interaction parameter was determined, χ(T) = 61.2T–1 – 0.1, based on the order-to-disorder transition temperatures of two symmetric triblocks using the calculated mean field theory result. The elastomeric mechanical behavior of two high molecular weight triblocks was characterized by tensile and elastic recovery experiments." @default.
• W2081214922 created "2016-06-24" @default.
• W2081214922 creator A5044358227 @default.
• W2081214922 creator A5061889011 @default.
• W2081214922 date "2011-10-14" @default.
• W2081214922 modified "2023-10-16" @default.
• W2081214922 title "Polylactide–Poly(6-methyl-ε-caprolactone)–Polylactide Thermoplastic Elastomers" @default.
• W2081214922 cites W1847731231 @default.
• W2081214922 cites W1964184511 @default.
• W2081214922 cites W1965254432 @default.
• W2081214922 cites W1969416531 @default.
• W2081214922 cites W1970875558 @default.
• W2081214922 cites W1973412177 @default.
• W2081214922 cites W1977566658 @default.
• W2081214922 cites W1987541306 @default.
• W2081214922 cites W1993705458 @default.
• W2081214922 cites W1995335187 @default.
• W2081214922 cites W1999552086 @default.
• W2081214922 cites W1999907439 @default.
• W2081214922 cites W2005804600 @default.
• W2081214922 cites W2013787151 @default.
• W2081214922 cites W2015733435 @default.
• W2081214922 cites W2016240465 @default.
• W2081214922 cites W2019315573 @default.
• W2081214922 cites W2021120142 @default.
• W2081214922 cites W2034566205 @default.
• W2081214922 cites W2047135363 @default.
• W2081214922 cites W2055144274 @default.
• W2081214922 cites W2055956577 @default.
• W2081214922 cites W2057763799 @default.
• W2081214922 cites W2062270453 @default.
• W2081214922 cites W2073395352 @default.
• W2081214922 cites W2077485810 @default.
• W2081214922 cites W2083446411 @default.
• W2081214922 cites W2086461131 @default.
• W2081214922 cites W2087327936 @default.
• W2081214922 cites W2087895908 @default.
• W2081214922 cites W2091160690 @default.
• W2081214922 cites W2094068820 @default.
• W2081214922 cites W2094424219 @default.
• W2081214922 cites W2102326686 @default.
• W2081214922 cites W2105518218 @default.
• W2081214922 cites W2106756509 @default.
• W2081214922 cites W2107836684 @default.
• W2081214922 cites W2124541353 @default.
• W2081214922 cites W2127210483 @default.
• W2081214922 cites W2129458302 @default.
• W2081214922 cites W2135102010 @default.
• W2081214922 cites W2141148505 @default.
• W2081214922 cites W2144863033 @default.
• W2081214922 cites W2160187718 @default.
• W2081214922 cites W2169391200 @default.
• W2081214922 cites W2170401727 @default.
• W2081214922 cites W2238658591 @default.
• W2081214922 cites W2317634079 @default.
• W2081214922 cites W2493119040 @default.
• W2081214922 cites W2614359702 @default.
• W2081214922 cites W2950867932 @default.
• W2081214922 cites W4230835856 @default.
• W2081214922 doi "https://doi.org/10.1021/ma201063t" @default.
• W2081214922 hasPublicationYear "2011" @default.
• W2081214922 type Work @default.
• W2081214922 sameAs 2081214922 @default.
• W2081214922 citedByCount "109" @default.
• W2081214922 countsByYear W20812149222012 @default.
• W2081214922 countsByYear W20812149222013 @default.
• W2081214922 countsByYear W20812149222014 @default.
• W2081214922 countsByYear W20812149222015 @default.
• W2081214922 countsByYear W20812149222016 @default.
• W2081214922 countsByYear W20812149222017 @default.
• W2081214922 countsByYear W20812149222018 @default.
• W2081214922 countsByYear W20812149222019 @default.
• W2081214922 countsByYear W20812149222020 @default.
• W2081214922 countsByYear W20812149222021 @default.
• W2081214922 countsByYear W20812149222022 @default.
• W2081214922 countsByYear W20812149222023 @default.
• W2081214922 crossrefType "journal-article" @default.
• W2081214922 hasAuthorship W2081214922A5044358227 @default.
• W2081214922 hasAuthorship W2081214922A5061889011 @default.
• W2081214922 hasConcept C119394753 @default.
• W2081214922 hasConcept C122865956 @default.
• W2081214922 hasConcept C158117686 @default.
• W2081214922 hasConcept C15920480 @default.
• W2081214922 hasConcept C159985019 @default.
• W2081214922 hasConcept C166940927 @default.
• W2081214922 hasConcept C188027245 @default.
• W2081214922 hasConcept C192562407 @default.
• W2081214922 hasConcept C196503311 @default.
• W2081214922 hasConcept C203897987 @default.
• W2081214922 hasConcept C2781111393 @default.
• W2081214922 hasConcept C2781247691 @default.
• W2081214922 hasConcept C38052585 @default.
• W2081214922 hasConcept C44228677 @default.
• W2081214922 hasConcept C521977710 @default.
• W2081214922 hasConcept C92328351 @default.
• W2081214922 hasConceptScore W2081214922C119394753 @default.
• W2081214922 hasConceptScore W2081214922C122865956 @default.
• W2081214922 hasConceptScore W2081214922C158117686 @default.

• next