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- W2081251917 abstract "The effect of pressure on the IR multiphoton dissociation of CDF3 at the 10R(24) CO2 laser line was studied in the broad substrate pressure range of 0.004-40 mbar. Careful observation was made of the effect in the low pressure region below 0.4 mbar where a single collision was expected within the duration of the laser pulse. In this region the dissociation yield decreased with an increase in the substrate pressure and the collisional quenching of the substrate excited above the dissociation threshold was dominant in IRMPA. Above this region, up to 27 mbar, the dissociation yield increased with an increase in the substrate pressure and then gradually decreased. The additive effect was also studied by adding Ar and N2 buffer gases. The effects at constant CDF3 pressure (1.33 mbar) were similar for both Ar and N2 up to 13.33 mbar, but N2 exerted greater quenching effects than Ar at higher pressures." @default.
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- W2081251917 date "1993-03-01" @default.
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- W2081251917 title "Pressure effects on IR multiphoton dissociation of CDF3" @default.
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- W2081251917 doi "https://doi.org/10.1016/1010-6030(93)87002-5" @default.
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