FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2081270873> ?p ?o ?g. }

• W2081270873 endingPage "1733" @default.
• W2081270873 startingPage "1727" @default.
• W2081270873 abstract "Abstract The t Bu 2 Sn‐bridged [1]troticenophane [(η 7 ‐C 7 H 6 )Ti(η 5 ‐C 5 H 4 )]Sn t Bu 2 ( 2 ) has been synthesized by low‐temperature salt elimination reaction between stoichiometric amounts of the dilithiated troticene [(η 7 ‐C 7 H 6 Li)Ti(η 5 ‐C 5 H 4 Li)] · pmdta ( 1 ; pmdta = N , N′ , N′ , N″ , N″ ‐pentamethyltriethylenetriamine) and t Bu 2 SnCl 2 . Compound 2 was isolated as a blue‐green crystalline solid in moderate yield and characterized by multinuclear 1 H, 13 C and 119 Sn NMR spectroscopy, UV/Vis spectroscopy and elemental analysis. Compound 2 and the co‐crystal 2· [(pmdta)LiCl] were characterized in the solid state by X‐ray diffraction analyses. The dihedral angles between the planes of the C 5 H 4 and C 7 H 6 rings are 16.3(3) and 17.2(1)°, respectively, for 2 and its co‐crystal. Compound 2 is the first monocrystalline structurally characterized heteroleptic stanna[1]troticenophane. The reaction of 2 with [Pt(PEt 3 ) 3 ] afforded the platinastanna[2]troticenophane 3 , in which the Pt 0 fragment was inserted by regioselective cleavage of the ipso ‐C 7 H 6 –Sn bond, as evidenced by 13 C NMR spectroscopy and X‐ray diffraction analysis. Compound 2 underwent thermal ring‐opening polymerization in the solid state to form poly(troticenylstannane) 4 . In solution and in the presence of n BuLi as initiator, 2 opens and reassembles to form the metallopolymer 5 . The polymeric nature of both 4 and 5 was determined by gel permeation chromatography." @default.
• W2081270873 created "2016-06-24" @default.
• W2081270873 creator A5034751002 @default.
• W2081270873 creator A5036558577 @default.
• W2081270873 creator A5062273930 @default.
• W2081270873 creator A5089476171 @default.
• W2081270873 date "2012-01-27" @default.
• W2081270873 modified "2023-10-16" @default.
• W2081270873 title "Synthesis, Reactivity and Ring‐Opening Polymerization of a Tin‐Bridged <i>ansa</i> ‐Cycloheptatrienyl‐Cyclopentadienyl Titanium Sandwich Complex" @default.
• W2081270873 cites W1496097339 @default.
• W2081270873 cites W1790859157 @default.
• W2081270873 cites W1965459878 @default.
• W2081270873 cites W1970442975 @default.
• W2081270873 cites W1971087443 @default.
• W2081270873 cites W1972982559 @default.
• W2081270873 cites W1976071630 @default.
• W2081270873 cites W1979170136 @default.
• W2081270873 cites W1981533217 @default.
• W2081270873 cites W1987756924 @default.
• W2081270873 cites W1996570183 @default.
• W2081270873 cites W1999076168 @default.
• W2081270873 cites W1999111015 @default.
• W2081270873 cites W1999967566 @default.
• W2081270873 cites W2001338086 @default.
• W2081270873 cites W2005240576 @default.
• W2081270873 cites W2005684248 @default.
• W2081270873 cites W2009093410 @default.
• W2081270873 cites W2011071481 @default.
• W2081270873 cites W2011926276 @default.
• W2081270873 cites W2013023551 @default.
• W2081270873 cites W2019143055 @default.
• W2081270873 cites W2019169999 @default.
• W2081270873 cites W2020968985 @default.
• W2081270873 cites W2025442780 @default.
• W2081270873 cites W2025827203 @default.
• W2081270873 cites W2027722800 @default.
• W2081270873 cites W2028319828 @default.
• W2081270873 cites W2031399971 @default.
• W2081270873 cites W2033870627 @default.
• W2081270873 cites W2037269142 @default.
• W2081270873 cites W2039049373 @default.
• W2081270873 cites W2045704941 @default.
• W2081270873 cites W2065635211 @default.
• W2081270873 cites W2067091310 @default.
• W2081270873 cites W2068884517 @default.
• W2081270873 cites W2085305336 @default.
• W2081270873 cites W2087041406 @default.
• W2081270873 cites W2088505722 @default.
• W2081270873 cites W2090559400 @default.
• W2081270873 cites W2101654608 @default.
• W2081270873 cites W2108400544 @default.
• W2081270873 cites W2125547677 @default.
• W2081270873 cites W2131350133 @default.
• W2081270873 cites W2133071321 @default.
• W2081270873 cites W2150834764 @default.
• W2081270873 cites W2153219073 @default.
• W2081270873 cites W2168532739 @default.
• W2081270873 cites W2950706093 @default.
• W2081270873 cites W4233823060 @default.
• W2081270873 cites W4239856299 @default.
• W2081270873 cites W4240721355 @default.
• W2081270873 doi "https://doi.org/10.1002/ejic.201101339" @default.
• W2081270873 hasPublicationYear "2012" @default.
• W2081270873 type Work @default.
• W2081270873 sameAs 2081270873 @default.
• W2081270873 citedByCount "20" @default.
• W2081270873 countsByYear W20812708732012 @default.
• W2081270873 countsByYear W20812708732013 @default.
• W2081270873 countsByYear W20812708732014 @default.
• W2081270873 countsByYear W20812708732015 @default.
• W2081270873 countsByYear W20812708732016 @default.
• W2081270873 countsByYear W20812708732019 @default.
• W2081270873 countsByYear W20812708732021 @default.
• W2081270873 countsByYear W20812708732022 @default.
• W2081270873 countsByYear W20812708732023 @default.
• W2081270873 crossrefType "journal-article" @default.
• W2081270873 hasAuthorship W2081270873A5034751002 @default.
• W2081270873 hasAuthorship W2081270873A5036558577 @default.
• W2081270873 hasAuthorship W2081270873A5062273930 @default.
• W2081270873 hasAuthorship W2081270873A5089476171 @default.
• W2081270873 hasConcept C142724271 @default.
• W2081270873 hasConcept C155647269 @default.
• W2081270873 hasConcept C161790260 @default.
• W2081270873 hasConcept C178790620 @default.
• W2081270873 hasConcept C181458950 @default.
• W2081270873 hasConcept C185592680 @default.
• W2081270873 hasConcept C188027245 @default.
• W2081270873 hasConcept C204787440 @default.
• W2081270873 hasConcept C2776910235 @default.
• W2081270873 hasConcept C44228677 @default.
• W2081270873 hasConcept C521977710 @default.
• W2081270873 hasConcept C525849907 @default.
• W2081270873 hasConcept C66974803 @default.
• W2081270873 hasConcept C71240020 @default.
• W2081270873 hasConcept C71924100 @default.
• W2081270873 hasConcept C8010536 @default.
• W2081270873 hasConceptScore W2081270873C142724271 @default.
• W2081270873 hasConceptScore W2081270873C155647269 @default.

• next