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- W2081275607 abstract "A general method for the enantioselective catalytic conjugate addition to acyclic α,β-unsaturated sulfones is described. Using metal-chelating α,β-unsaturated pyridyl sulfones as substrates, the rhodium-catalyzed chiraphos-mediated addition of organoboric acids takes place in excellent yield and high enantioselectivity. The subsequent elimination of the pyridylsulfonyl group by Julia−Kociensky olefination provides a novel approach to the enantioselective synthesis of allylic substituted alkenes." @default.
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- W2081275607 date "2004-07-31" @default.
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- W2081275607 title "Rhodium-Catalyzed Enantioselective Conjugate Addition of Organoboronic Acids to α,β-Unsaturated Sulfones" @default.
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- W2081275607 doi "https://doi.org/10.1021/ol048690p" @default.
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