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- W2081293311 abstract "Use of the fragrance 6-methylcoumarin (6-MC) in cosmetic products has declined significantly due to numerous reports of photoallergic contact dermatitis associated with its use. We have determined that 6-MC undergoes direct photolysis with an estimated half-life of 83 minutes when illuminated with mid-latitude U.S., noon-centered, equinox sunlight and a quantum yield for photolysis at 313 nm of phi = 3 x 10(-3). The work presented here also provides evidence that singlet molecular oxygen ((1)O2) is formed in illuminated solutions containing 6-MC. An estimated value of phi = 0.01 is reported for the (1)O2 quantum yield at 313 nm. Formation of (1)O2 is significant because it is known to react with a variety of biomolecules and it is possible that (1)O2 formation is at least partially responsible for reports of 6-MC photoallergenicity and phototoxicity." @default.
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- W2081293311 date "1997-06-01" @default.
- W2081293311 modified "2023-09-24" @default.
- W2081293311 title "Photochemical Formation of Singlet Molecular Oxygen (1O2) in Illuminated6-Methylcoumarin Solutions" @default.
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- W2081293311 doi "https://doi.org/10.1006/bbrc.1997.6848" @default.
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