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- W2081323504 abstract "It is shown that in certain “critical” conditions created in a chromatographic column the flexible polymer chains perform a phase transition of the first kind abruptly penetrating from the free volume of the mobile eluent into the narrow pores of the adsorbent. The experimental data on the chromatography of PS samples in a mixed eluent at different temperatures are reviewed showing that the width of the transition tends to zero as the MW of polystyrene increases. The legitimacy of using in chromatography the concepts “mobile and immobile phases” in terms of the theory of phase transitions is discussed." @default.
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- W2081323504 date "1989-01-01" @default.
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- W2081323504 title "Phase transitions in liquid chromatography of polymers" @default.
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- W2081323504 doi "https://doi.org/10.1016/0032-3950(89)90157-3" @default.
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