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- W2081400644 abstract "The proton NMR shifts Δ σ of the water molecule co-ordinated to the cation in the crystal hexahydrate of magnesium chloride as well as in the aqueous solution of aluminium chloride relative to the pure liquid water at 0°C, have been observed. These shifts would largely depend on the component of the electric field F // (e.s.u.) parallel to the direction of the OH bond of a water molecule, produced by the surrounding ions or neighbouring water molecules. The observed shifts Δ σ are found to depend practically linearly on the calculated values of F // , and can be represented approximately by an empirical formula Δ σ=5.0×10 -6 F // +4.2 (ppm), where H→O direction being taken to be positive." @default.
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- W2081400644 date "1973-11-01" @default.
- W2081400644 modified "2023-10-01" @default.
- W2081400644 title "The Proton NMR Shifts and the Local Electric Field in Solid MgCl<sub>2</sub>·6H<sub>2</sub>O and in AlCl<sub>3</sub> Solution" @default.
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- W2081400644 doi "https://doi.org/10.1143/jpsj.35.1346" @default.
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