Matches in SemOpenAlex for { <https://semopenalex.org/work/W2081420565> ?p ?o ?g. }
- W2081420565 endingPage "2208" @default.
- W2081420565 startingPage "2202" @default.
- W2081420565 abstract "The highly luminescent polynuclear CuI iodide complexes, [(Cu2I2)(4,4′-bipy)(PCy3)2]2 · 4H2O (1), [(Cu2I2)(4,4′-bipy)(PCy3)2]∞ (2), [(Cu2I2)(4,4′-bipy)(dcpm)]∞ (3) and [(Cu2I2)(4,4′-bipy)(dppm)]∞ (4), were prepared by reacting CuI with tricyclohexylphosphine (PCy3), bis(dicyclohexylphosphino)methane (dcpm) or bis(diphenylphosphino)methane (dppm) and 4,4′-bipyridine (4,4′-bipy), and their structures were determined by X-ray crystal analysis. The reported complexes [CuClPCy3]2 (5) and [CuIPCy3]2 (6) were also prepared for comparison. In solid state, complexes 1–6 display intense long-lived phosphorescence with λmax at 605, 565, 640, 570, 430 and 450 nm at room temperature, and the solid-state emission quantum yields are 0.11, 0.20, 0.29, 0.35, 0.67 and 0.83, respectively. The relatively high-energy emissions of 5 and 6 are attributed to arising from metal-centered MC (3d → 4s, 4p) excited state, while the low-energy emissions of 1–4 are assigned to a metal-to-ligand charge transfer (d → π∗ MLCT) excited state." @default.
- W2081420565 created "2016-06-24" @default.
- W2081420565 creator A5014172706 @default.
- W2081420565 creator A5036458797 @default.
- W2081420565 creator A5038667092 @default.
- W2081420565 creator A5040977229 @default.
- W2081420565 creator A5042560788 @default.
- W2081420565 creator A5061345249 @default.
- W2081420565 creator A5065597851 @default.
- W2081420565 creator A5066685111 @default.
- W2081420565 creator A5070554076 @default.
- W2081420565 creator A5085462851 @default.
- W2081420565 date "2008-06-01" @default.
- W2081420565 modified "2023-10-03" @default.
- W2081420565 title "Synthesis, structures and photophysical properties of polynuclear copper(I) iodide complexes containing phosphine and 4,4′-bipyridine ligands" @default.
- W2081420565 cites W1963974948 @default.
- W2081420565 cites W1964001587 @default.
- W2081420565 cites W1970528938 @default.
- W2081420565 cites W1985055718 @default.
- W2081420565 cites W2001169476 @default.
- W2081420565 cites W2006809351 @default.
- W2081420565 cites W2007078309 @default.
- W2081420565 cites W2008684086 @default.
- W2081420565 cites W2014580773 @default.
- W2081420565 cites W2023271753 @default.
- W2081420565 cites W2024706479 @default.
- W2081420565 cites W2028677510 @default.
- W2081420565 cites W2031012017 @default.
- W2081420565 cites W2039817306 @default.
- W2081420565 cites W2043917068 @default.
- W2081420565 cites W2044451314 @default.
- W2081420565 cites W2049242948 @default.
- W2081420565 cites W2055482935 @default.
- W2081420565 cites W2066665417 @default.
- W2081420565 cites W2071118968 @default.
- W2081420565 cites W2071170639 @default.
- W2081420565 cites W2074541229 @default.
- W2081420565 cites W2080260516 @default.
- W2081420565 cites W2087182711 @default.
- W2081420565 cites W2160415689 @default.
- W2081420565 cites W3138922496 @default.
- W2081420565 doi "https://doi.org/10.1016/j.poly.2008.03.026" @default.
- W2081420565 hasPublicationYear "2008" @default.
- W2081420565 type Work @default.
- W2081420565 sameAs 2081420565 @default.
- W2081420565 citedByCount "35" @default.
- W2081420565 countsByYear W20814205652012 @default.
- W2081420565 countsByYear W20814205652013 @default.
- W2081420565 countsByYear W20814205652014 @default.
- W2081420565 countsByYear W20814205652015 @default.
- W2081420565 countsByYear W20814205652016 @default.
- W2081420565 countsByYear W20814205652018 @default.
- W2081420565 countsByYear W20814205652020 @default.
- W2081420565 countsByYear W20814205652023 @default.
- W2081420565 crossrefType "journal-article" @default.
- W2081420565 hasAuthorship W2081420565A5014172706 @default.
- W2081420565 hasAuthorship W2081420565A5036458797 @default.
- W2081420565 hasAuthorship W2081420565A5038667092 @default.
- W2081420565 hasAuthorship W2081420565A5040977229 @default.
- W2081420565 hasAuthorship W2081420565A5042560788 @default.
- W2081420565 hasAuthorship W2081420565A5061345249 @default.
- W2081420565 hasAuthorship W2081420565A5065597851 @default.
- W2081420565 hasAuthorship W2081420565A5066685111 @default.
- W2081420565 hasAuthorship W2081420565A5070554076 @default.
- W2081420565 hasAuthorship W2081420565A5085462851 @default.
- W2081420565 hasConcept C115624301 @default.
- W2081420565 hasConcept C116569031 @default.
- W2081420565 hasConcept C121332964 @default.
- W2081420565 hasConcept C148869448 @default.
- W2081420565 hasConcept C161790260 @default.
- W2081420565 hasConcept C170493617 @default.
- W2081420565 hasConcept C178790620 @default.
- W2081420565 hasConcept C179104552 @default.
- W2081420565 hasConcept C181500209 @default.
- W2081420565 hasConcept C181817918 @default.
- W2081420565 hasConcept C184779094 @default.
- W2081420565 hasConcept C185592680 @default.
- W2081420565 hasConcept C2777716191 @default.
- W2081420565 hasConcept C2777907610 @default.
- W2081420565 hasConcept C2777981386 @default.
- W2081420565 hasConcept C2778870691 @default.
- W2081420565 hasConcept C2779336533 @default.
- W2081420565 hasConcept C49040817 @default.
- W2081420565 hasConcept C544153396 @default.
- W2081420565 hasConcept C544778455 @default.
- W2081420565 hasConcept C55493867 @default.
- W2081420565 hasConcept C62520636 @default.
- W2081420565 hasConcept C75473681 @default.
- W2081420565 hasConcept C8010536 @default.
- W2081420565 hasConcept C91881484 @default.
- W2081420565 hasConceptScore W2081420565C115624301 @default.
- W2081420565 hasConceptScore W2081420565C116569031 @default.
- W2081420565 hasConceptScore W2081420565C121332964 @default.
- W2081420565 hasConceptScore W2081420565C148869448 @default.
- W2081420565 hasConceptScore W2081420565C161790260 @default.
- W2081420565 hasConceptScore W2081420565C170493617 @default.
- W2081420565 hasConceptScore W2081420565C178790620 @default.
- W2081420565 hasConceptScore W2081420565C179104552 @default.