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• W2081436812 abstract "A melt encasement (fluxing) technique has been used to solidify the congruently melting intermetallic βNi3Ge from its deeply undercooled parent melt. High speed photography and a photo-diode technique have been used to measure the resulting growth velocity. The maximum undercooling achieved was 362 K, wherein a growth velocity of 3.55 m s−1 was recorded. At an undercooling of 168 K, an abrupt increase in the gradient of the velocity-undercooling curve is observed and this is attributed to a transition from growth of the ordered L12 compound at low undercooling, to growth of the fully disordered compound at high undercooling. A change in the microstructure, from a distribution of very coarse (700 μm), randomly oriented grains to a fine-grained structure (15–20 μm) with a large number of low-angle grain boundaries is observed coincident with this transition in the velocity-undercooling curve, a grain refinement pattern that is different to that observed either in deeply undercooled solid solutions or other intermetallics. This transition is ascribed to a recovery and recrystallisation process in the disordered phase due to the low post-recalescence cooling rate." @default.
• W2081436812 created "2016-06-24" @default.
• W2081436812 creator A5002147781 @default.
• W2081436812 creator A5086740474 @default.
• W2081436812 date "2011-11-02" @default.
• W2081436812 modified "2023-09-25" @default.
• W2081436812 title "Disorder trapping during the solidification of βNi3Ge from its deeply undercooled melt" @default.
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• W2081436812 doi "https://doi.org/10.1007/s10853-011-6062-y" @default.
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