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- W2081441569 abstract "The inhibiting activity of poly (2-methyl-5-ethynylpyridine) (PEP) has been studied in the cumene oxidation reaction initiated by azobisisobutyronitrile at 55–65°C. According to the kinetic data the reaction between RO2 radical and PEP is irreversible. About 12% of the most active macromolecules of PEP react during the induction period followed by retarded oxidation of cumene. The quantity of terminated peroxy radicals reaches 1.5 per molecule of the inhibitor. This quantity is not altered when PEP concentration changes. Macromolecules of PEP differ in their radical reactivity. An increase of PEP molecular weight leads to the increase in PEP reactivity and in the fraction of active molecules. The paramagnetic centers of PEP interact with peroxy radicals at the maximum rate and disappear at the initial stage of oxidation." @default.
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- W2081441569 date "2007-03-08" @default.
- W2081441569 modified "2023-09-23" @default.
- W2081441569 title "The study of the inhibiting activity of poly (2-methyl-5-ethynylpyridine) during initiated oxidation of cumene" @default.
- W2081441569 doi "https://doi.org/10.1002/polc.5070400112" @default.
- W2081441569 hasPublicationYear "2007" @default.
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