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• W2081444562 abstract "The temperature dependence of the 15 N and 133 Cs NMR spin-lattice relaxation times, the 15 N spin-spin relaxation time, and the 15 N and 133 Cs spectra of CsNO 2 was observed in the plastic phase (209.2 < T < 673 K (m. p.)) and the low-temperature phase (Phase II). In Phase II we found the NO - 2 180°-flip, which could be attributed to the anomalous increase of the heat capacity curve, and determined the activation energy of this motion to be 8.7-11.7 kJ mol -1 . The 15 N and 133 Cs spectra in this phase are inconsistent with the reported crystal structure R3̅m and can be explained by lower crystal symmetry. In the plastic phase we detected a new anionic motion with 11 kJ mol -1 , an isotropic NO - 2 reorientation with 8.5-9 kJ mol -1 , and ionic self-diffusion with 47 kJ mol -1 . The presence of ionic self-diffusion was confirmed by measuring the electrical conductivity." @default.
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• W2081444562 date "1996-06-01" @default.
• W2081444562 modified "2023-10-18" @default.
• W2081444562 title "¹⁵N and ¹³³Cs Solid NMR Studies on Ionic Dynamics in Plastic CsNO₂" @default.
• W2081444562 doi "https://doi.org/10.1515/zna-1996-5-668" @default.
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