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- W2081481990 abstract "Abstract A new chiral polyoxometalates based functionalized material comprising Keggin type mono manganese substituted phosphotungstate and enantiopure R -(−)-1-cyclohexylethylamine was synthesized in an aqueous media by simple ligand substitution method. The POM-based synthesized material was systematically characterized in solid as well as solution by various physicochemical techniques such as elemental analysis, TGA, UV–Vis, FT-IR, ESR and multinuclear solution NMR ( 31 P, 1 H, 13 C). The presence of chirality in the synthesized material was confirmed by CD spectroscopy and polarimeter. The above study reveals the attachment of R -(−)-1-cyclohexylethylamine to Keggin type mono manganese substituted phosphotungstate through N → Mn dative bond. It also indicates the retainment of Keggin unit and chirality in the synthesized material." @default.
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- W2081481990 date "2012-03-01" @default.
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- W2081481990 title "Functionalization of Keggin type manganese substituted phosphotungstate by R-(−)-1-cyclohexylethylamine: Synthesis and characterization" @default.
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- W2081481990 doi "https://doi.org/10.1016/j.ica.2011.10.017" @default.
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