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• W2081491805 abstract "Abstract A hybrid molecule between BEDT-TTF and TTC 1 -TTF (tetrakis(methylthio)-TTF; C 1 TET-TTF (bis(methylthio)ethylenedithio-TTF), gave cation radical salts with PF 6 , AsF 6 , and Sb 2 F 11 anions. Two PF 6 and two AsF 6 salts were electrochemically prepared in methanol or ethanol, and all of the four showed metallic temperature dependence of d.c. resistivity at around room temperature. These four salts are isomorphic, however, there are slight differences in the anion arrangement which is dependent on the solvent used. The salts from ethanol gave narrower EPR line widths than those from methanol at r.t.. The temperature dependence of EPR intensity for the four salts showed a similar fashion to one another, though the four-probe resistivity measurements exhibited a variety of temperature dependences. Unexpectedly, the Sb 2 F 11 salt was obtained by the electrolysis with TBA·SbF 6 in methanol, and showed semiconducting behavior. The composition was (C 1 TET-TTF) 4 Sb 2 F 11 with a binuclear anion of two Sb centered octahedra sharing a F atom." @default.
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• W2081491805 date "1991-05-01" @default.
• W2081491805 modified "2023-09-30" @default.
• W2081491805 title "C1 TET-TTF salts with octahedral anions" @default.
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• W2081491805 doi "https://doi.org/10.1016/0379-6779(91)91934-3" @default.
• W2081491805 hasPublicationYear "1991" @default.
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