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- W2081522329 abstract "As part of an extended research program concerning the phase behaviour and thermodynamics of fluid mixtures at high pressure, the liquid-liquid phase equilibria in the binary system 1,2,3,4-tetrahydronaphthalene + H2O, decahydronaphthalene(cis) + H2O, and decahydro-naphthalene(trans) + H2O as well as in the ternary system 1,2,3,4-tetrahydronaphthalene + decahydronaphthalene(trans) + H2O were measured in the temperature range from 280°C to 420°C and at pressures up to 2600 bar with an optical high temperature high pressure autoclave using magnetic stirring. All systems show upper solution temperatures that increase with increasing pressure. — The results are compared with data obtained for the liquid-liquid phase equilibria in the system methane + trifluoromethane at temperatures between — 118°C and — 95°C and at pressures up to 1900 bar in a high pressure low temperature autoclave. This system also exhibits upper solution temperatures that increase with increasing pressure. Im Rahmen von Untersuchungen zur Thermodynamik fluider Mischsysteme wurden die Flüssig-Flüssig-Phasengleichgewichte in den binären Systemen 1, 2, 3, 4-Tetrahydronaphthalin + H2O, cis-Dekahydronaphthalin + H2O und trans-Dekahydronaphthalin + H2O sowie in dem ternären System 1, 2, 3, 4-Tetrahydronaphthalin + trans-Dekahydronaphthalin + H2O im Temperaturbereich von 280 bis 420°C und bei Drücken bis maximal 2600 bar in einer optischen Hochdruck-Hochtemperatur-Meßzelle ausgemessen. Bei allen Systemen treten obere Entmischungstemperaturen auf, die mit steigendem Druck ansteigen. — Die Ergebnisse werden mit Meßdaten verglichen, die für die Flüssig-Flüssig-Phasengleichgewichte in dem System Methan + Trifluormethan im Temperaturbereich von — 118 bis −95°C und bei Drücken bis 1900 bar in einer Hochdruck-Tieftemperatur-Meßzelle gefunden wurden. Auch dieses System besitzt obere Entmischungstemperaturen, die mit steigendem Druck ansteigen." @default.
- W2081522329 created "2016-06-24" @default.
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- W2081522329 date "1977-10-01" @default.
- W2081522329 modified "2023-09-26" @default.
- W2081522329 title "Fluid Mixtures at High Pressures. Liquid-Liquid Phase Equilibria and Critical Phenomena in the Systems 1,2,3,4-Tetrahydronaphthalene + Water, Decahydronaphthalene(cis) + Water, Decahydronaphthalene(trans) + Water, and Methane + Trifluoromethane up to 2600" @default.
- W2081522329 cites W1510819776 @default.
- W2081522329 doi "https://doi.org/10.1002/bbpc.19770811050" @default.
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