Matches in SemOpenAlex for { <https://semopenalex.org/work/W2081532858> ?p ?o ?g. }
- W2081532858 endingPage "10920" @default.
- W2081532858 startingPage "10913" @default.
- W2081532858 abstract "Recent single-molecule experiments indicated that thioethers (dialkyl sulfides) on gold surfaces act as thermally- or mechanically activated molecular rotors, although the mechanisms for these phenomena are not yet clearly understood. Here we present theoretical and experimental investigations of the rotational dynamics of these thioether molecules. Single-molecule studies utilizing low-temperature scanning tunneling microscopy allowed us to determine rotational rates and activation energies for the rotation of symmetric dialkyl sulfides. It was found that the rotational energy barriers increased as a function of alkyl chain length but then quickly saturated. Molecular dynamics simulations have also been performed in order to understand the molecular rotations of thioethers, and our theoretical calculations agree well with experimental observations. It is argued that the observed rotational dynamics of dialkyl sulfides are determined by the effective interactions with the surface and the flexibility of the alkyl chains. These results suggest possible ways to control and utilize thioether rotors at the single-molecule level." @default.
- W2081532858 created "2016-06-24" @default.
- W2081532858 creator A5003764007 @default.
- W2081532858 creator A5030045624 @default.
- W2081532858 creator A5048289852 @default.
- W2081532858 creator A5078222261 @default.
- W2081532858 creator A5083739979 @default.
- W2081532858 date "2009-04-24" @default.
- W2081532858 modified "2023-10-16" @default.
- W2081532858 title "Dynamics of Thioether Molecular Rotors: Effects of Surface Interactions and Chain Flexibility" @default.
- W2081532858 cites W1559264985 @default.
- W2081532858 cites W1968328510 @default.
- W2081532858 cites W1973858916 @default.
- W2081532858 cites W1985758219 @default.
- W2081532858 cites W1989578084 @default.
- W2081532858 cites W1992596389 @default.
- W2081532858 cites W1993031348 @default.
- W2081532858 cites W2000420238 @default.
- W2081532858 cites W2004412281 @default.
- W2081532858 cites W2008084491 @default.
- W2081532858 cites W2012499551 @default.
- W2081532858 cites W2013193999 @default.
- W2081532858 cites W2023390615 @default.
- W2081532858 cites W2029904934 @default.
- W2081532858 cites W2030971064 @default.
- W2081532858 cites W2032628506 @default.
- W2081532858 cites W2038100642 @default.
- W2081532858 cites W2045287626 @default.
- W2081532858 cites W2058813131 @default.
- W2081532858 cites W2061039525 @default.
- W2081532858 cites W2067049601 @default.
- W2081532858 cites W2067365086 @default.
- W2081532858 cites W2067822713 @default.
- W2081532858 cites W2075093151 @default.
- W2081532858 cites W2079572802 @default.
- W2081532858 cites W2080734498 @default.
- W2081532858 cites W2082056601 @default.
- W2081532858 cites W2087623017 @default.
- W2081532858 cites W2088810112 @default.
- W2081532858 cites W2089154785 @default.
- W2081532858 cites W2091233845 @default.
- W2081532858 cites W2099392831 @default.
- W2081532858 cites W2121821664 @default.
- W2081532858 cites W2125319072 @default.
- W2081532858 cites W2148405700 @default.
- W2081532858 cites W2154395440 @default.
- W2081532858 cites W2166454051 @default.
- W2081532858 cites W2171696630 @default.
- W2081532858 cites W2172287039 @default.
- W2081532858 cites W2949437940 @default.
- W2081532858 cites W4211203651 @default.
- W2081532858 cites W4235866119 @default.
- W2081532858 cites W4384652465 @default.
- W2081532858 doi "https://doi.org/10.1021/jp9017844" @default.
- W2081532858 hasPublicationYear "2009" @default.
- W2081532858 type Work @default.
- W2081532858 sameAs 2081532858 @default.
- W2081532858 citedByCount "34" @default.
- W2081532858 countsByYear W20815328582012 @default.
- W2081532858 countsByYear W20815328582013 @default.
- W2081532858 countsByYear W20815328582014 @default.
- W2081532858 countsByYear W20815328582015 @default.
- W2081532858 countsByYear W20815328582016 @default.
- W2081532858 countsByYear W20815328582018 @default.
- W2081532858 countsByYear W20815328582019 @default.
- W2081532858 countsByYear W20815328582022 @default.
- W2081532858 crossrefType "journal-article" @default.
- W2081532858 hasAuthorship W2081532858A5003764007 @default.
- W2081532858 hasAuthorship W2081532858A5030045624 @default.
- W2081532858 hasAuthorship W2081532858A5048289852 @default.
- W2081532858 hasAuthorship W2081532858A5078222261 @default.
- W2081532858 hasAuthorship W2081532858A5083739979 @default.
- W2081532858 hasConcept C105795698 @default.
- W2081532858 hasConcept C121332964 @default.
- W2081532858 hasConcept C145912823 @default.
- W2081532858 hasConcept C147597530 @default.
- W2081532858 hasConcept C159467904 @default.
- W2081532858 hasConcept C178790620 @default.
- W2081532858 hasConcept C185592680 @default.
- W2081532858 hasConcept C192562407 @default.
- W2081532858 hasConcept C24890656 @default.
- W2081532858 hasConcept C2779444094 @default.
- W2081532858 hasConcept C2780263894 @default.
- W2081532858 hasConcept C2780598303 @default.
- W2081532858 hasConcept C2992358367 @default.
- W2081532858 hasConcept C32909587 @default.
- W2081532858 hasConcept C33923547 @default.
- W2081532858 hasConcept C59593255 @default.
- W2081532858 hasConcept C71240020 @default.
- W2081532858 hasConceptScore W2081532858C105795698 @default.
- W2081532858 hasConceptScore W2081532858C121332964 @default.
- W2081532858 hasConceptScore W2081532858C145912823 @default.
- W2081532858 hasConceptScore W2081532858C147597530 @default.
- W2081532858 hasConceptScore W2081532858C159467904 @default.
- W2081532858 hasConceptScore W2081532858C178790620 @default.
- W2081532858 hasConceptScore W2081532858C185592680 @default.
- W2081532858 hasConceptScore W2081532858C192562407 @default.
- W2081532858 hasConceptScore W2081532858C24890656 @default.