Matches in SemOpenAlex for { <https://semopenalex.org/work/W2081567441> ?p ?o ?g. }
- W2081567441 endingPage "6214" @default.
- W2081567441 startingPage "6207" @default.
- W2081567441 abstract "Resonance enhanced second harmonic generation (SHG) has been used to identify solvation mechanisms at different solid/liquid interfaces. Solvation interactions are characterized as being either nonspecific and averaged over the entire solute cavity or specific, referring to localized, directional interactions between a solute and its surroundings. SHG spectra report the electronic structure of solutes adsorbed to silica/organic solvent interfaces, and different solutes are chosen to probe either interfacial polarity or interfacial hydrogen bond donating/accepting opportunities. SHG results show that interfacial polarity probed by p-nitroanisole depends sensitively on solvent structure, whereas hydrogen bonding interactions probed by indoline are insensitive to solvent identity and instead are dominated by the hydrogen bond donating properties of the polar silica substrate. The bulk solvation interactions were modeled with a series of ab initio calculations that characterized solute electronic structure within a dielectric continuum and in the presence of explicit, individual solvent molecules. Collectively, these measurements and calculations create a comprehensive picture of how solvation mechanisms vary at different polar, solid surfaces." @default.
- W2081567441 created "2016-06-24" @default.
- W2081567441 creator A5017764387 @default.
- W2081567441 creator A5033552854 @default.
- W2081567441 date "2009-04-14" @default.
- W2081567441 modified "2023-10-06" @default.
- W2081567441 title "Differentiating Solvation Mechanisms at Polar Solid/Liquid Interfaces" @default.
- W2081567441 cites W121720478 @default.
- W2081567441 cites W1964463929 @default.
- W2081567441 cites W1965538774 @default.
- W2081567441 cites W1966584454 @default.
- W2081567441 cites W1971645994 @default.
- W2081567441 cites W1971968732 @default.
- W2081567441 cites W1979857132 @default.
- W2081567441 cites W1981544607 @default.
- W2081567441 cites W1989196243 @default.
- W2081567441 cites W1993169515 @default.
- W2081567441 cites W1998442411 @default.
- W2081567441 cites W2001865592 @default.
- W2081567441 cites W2006348340 @default.
- W2081567441 cites W2008419284 @default.
- W2081567441 cites W2010433544 @default.
- W2081567441 cites W2014118109 @default.
- W2081567441 cites W2015137763 @default.
- W2081567441 cites W2015946428 @default.
- W2081567441 cites W2017744447 @default.
- W2081567441 cites W2025705968 @default.
- W2081567441 cites W2029413909 @default.
- W2081567441 cites W2031637556 @default.
- W2081567441 cites W2036075887 @default.
- W2081567441 cites W2039385680 @default.
- W2081567441 cites W2040888223 @default.
- W2081567441 cites W2041323785 @default.
- W2081567441 cites W2041638983 @default.
- W2081567441 cites W2042276199 @default.
- W2081567441 cites W2045278128 @default.
- W2081567441 cites W2050650592 @default.
- W2081567441 cites W2051433899 @default.
- W2081567441 cites W2052412840 @default.
- W2081567441 cites W2052767840 @default.
- W2081567441 cites W2053678134 @default.
- W2081567441 cites W2055459945 @default.
- W2081567441 cites W2057003691 @default.
- W2081567441 cites W2066512277 @default.
- W2081567441 cites W2069798494 @default.
- W2081567441 cites W2073690435 @default.
- W2081567441 cites W2078986879 @default.
- W2081567441 cites W2080087866 @default.
- W2081567441 cites W2083564032 @default.
- W2081567441 cites W2084384492 @default.
- W2081567441 cites W2086862680 @default.
- W2081567441 cites W2089040865 @default.
- W2081567441 cites W2091908682 @default.
- W2081567441 cites W2117463668 @default.
- W2081567441 cites W2120962039 @default.
- W2081567441 cites W2121242766 @default.
- W2081567441 cites W2131754023 @default.
- W2081567441 cites W2138748398 @default.
- W2081567441 cites W2143371913 @default.
- W2081567441 cites W2167741273 @default.
- W2081567441 cites W2170838656 @default.
- W2081567441 cites W2314877582 @default.
- W2081567441 cites W2323425605 @default.
- W2081567441 cites W2326203395 @default.
- W2081567441 cites W2335635236 @default.
- W2081567441 doi "https://doi.org/10.1021/ja810117f" @default.
- W2081567441 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19366208" @default.
- W2081567441 hasPublicationYear "2009" @default.
- W2081567441 type Work @default.
- W2081567441 sameAs 2081567441 @default.
- W2081567441 citedByCount "36" @default.
- W2081567441 countsByYear W20815674412012 @default.
- W2081567441 countsByYear W20815674412013 @default.
- W2081567441 countsByYear W20815674412014 @default.
- W2081567441 countsByYear W20815674412015 @default.
- W2081567441 countsByYear W20815674412016 @default.
- W2081567441 countsByYear W20815674412017 @default.
- W2081567441 countsByYear W20815674412018 @default.
- W2081567441 countsByYear W20815674412019 @default.
- W2081567441 countsByYear W20815674412020 @default.
- W2081567441 countsByYear W20815674412021 @default.
- W2081567441 countsByYear W20815674412023 @default.
- W2081567441 crossrefType "journal-article" @default.
- W2081567441 hasAuthorship W2081567441A5017764387 @default.
- W2081567441 hasAuthorship W2081567441A5033552854 @default.
- W2081567441 hasConcept C112887158 @default.
- W2081567441 hasConcept C121332964 @default.
- W2081567441 hasConcept C1276947 @default.
- W2081567441 hasConcept C147597530 @default.
- W2081567441 hasConcept C147789679 @default.
- W2081567441 hasConcept C148093993 @default.
- W2081567441 hasConcept C1491633281 @default.
- W2081567441 hasConcept C159467904 @default.
- W2081567441 hasConcept C178790620 @default.
- W2081567441 hasConcept C185592680 @default.
- W2081567441 hasConcept C2777361361 @default.
- W2081567441 hasConcept C2780471494 @default.
- W2081567441 hasConcept C29705727 @default.