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- W2081570355 abstract "Water vapour isotherms at 35° were measured on two samples of thorium dioxide, one crystalline and the other an amorphous gel. Specific surface areas and pore size distributions were estimated and compared with those obtained from nitrogen adsorption at −196°. The effect of thermal treatment on both samples was also investigated at 35–500°. It was shown that the adsorption of water vapour on thoria gel is purely physical in nature, and that the gel surface is characterised by the existence of pores of very particular sizes, namely of hydraulic radii 4–6 Ǎ. On the other hand, water seems to interact chemically with the surface of the crystalline sample. In this case the specific surface area could not be evaluated from the adsorption branch of the isotherm, but was successfully evaluated through the application of the ‘corrected modelless’ method to the desorption branch of the water isotherms. This gave the surface area of the total pore system which was found to be in good agreement with the B.E.T.-nitrogen area." @default.
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- W2081570355 date "2007-05-04" @default.
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- W2081570355 title "Surface area and pore structure of thorium dioxide" @default.
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- W2081570355 doi "https://doi.org/10.1002/jctb.5010200704" @default.
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