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- W2081603688 abstract "N-Benzyloxycarbonyl-2,5-dideoxy-2,5-imino-3,4-O-isopropylidene-l-ribose 12a has been converted into (1R,2S,6R,7S,7aS)-5 and (1R,2S,6S,7R,7aR)-1,2,6,7-tetrahydroxypyrrolidin-5-ones 6 and (1R,2S,6S,7S,7aS)-7 and (1R,2S,6R,7R,7aS)-1,2,6,7-tetrahydroxypyrrolizidines 8 following stereoselective paths. These new compounds have been assayed for their inhibitory activities towards 25 glycosidases. Pyrrolizidines 7 and 8 are moderate but selective inhibitors of amyloglucosidase from Rhizopus mold (7: IC50=130 μM, Ki=120 μM; 8: IC50=200 μM, Ki=180 μM, mixed type of inhibition)." @default.
- W2081603688 created "2016-06-24" @default.
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- W2081603688 date "2004-01-01" @default.
- W2081603688 modified "2023-10-10" @default.
- W2081603688 title "Stereoselective synthesis of novel tetrahydroxypyrrolizidines" @default.
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- W2081603688 doi "https://doi.org/10.1016/j.tetasy.2003.11.022" @default.
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