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- W2081664892 abstract "Two weak stretching bands, ν1 + 3ν3 and 3ν1 + ν3, of the sulfur dioxide molecule have been recorded at high resolution and analyzed for the first time with using a Fourier transform Bruker IFS-120 HR interferometer. About 1000 transitions with Jmax. = 51, Kamax.=16, and 900 transitions with Jmax. = 53, Kamax.=16 have been assigned to the bands ν1 + 3ν3 and 3ν1 + ν3, respectively. Analysis of the recorded spectra was made using the model of isolated vibrational states. Parameters obtained from the fit reproduce the initial experimental ro-vibrational energies with the rms deviation of 0.0006 and 0.0012 cm−1 for the bands, 3ν1 + ν3 and ν1 + 3ν3, respectively. The problem of determination of the intramolecular potential function of SO2 is discussed." @default.
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- W2081664892 date "2009-10-01" @default.
- W2081664892 modified "2023-10-16" @default.
- W2081664892 title "On the high resolution spectroscopy and intramolecular potential function of SO2" @default.
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- W2081664892 doi "https://doi.org/10.1016/j.jms.2009.07.005" @default.
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