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- W2081714114 abstract "A study has been made of the properties of polyelectrolyte complexes (PEC) of nonequimolar composition as exemplified by those formed by poly(N-ethyl-4-vinyl-pyridinium bromide) (PVP C 2 H 5 Br) and polymethacrylic acid (PMAA) in acid media. It has been found that such PEC have a property in common in that they dissolve in neutral and weakly basic media, whereas simple mixing of polyelectrolytes in any ratios at pH at which both polymer components are completely charged (pH ≈ 7) leads only to formation of equimolar PEC that are insoluble in water. The dissolution of PEC is observed over a sufficiently wide composition range 2·5 < PVPB:PMMA < 5, and does not involve dissociation of PEC into components. The mechanism of formation of water-soluble polycomplexes is considered, and a model of such polycomplexes is suggested." @default.
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- W2081714114 date "1978-01-01" @default.
- W2081714114 modified "2023-09-26" @default.
- W2081714114 title "Study of water soluble polyelectrolyte complexes of nonequimolar composition" @default.
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- W2081714114 doi "https://doi.org/10.1016/0032-3950(78)90059-x" @default.
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