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- W2081719565 abstract "Fragmentation patterns are rationized from fast atom bombardment spectra of thirty glucuronides containing seven different kinds of glycosidic linkages. In general negative ion spectra provided more definitive molecular weights and consistent fragment ions, however positive ion spectra are preferred for quaternary ammonium-, carbinolamine and oxime-linked glucuronides. Two bond cleaages appear to be class characteristic, both involving loss of the glucuronic acid moiety accompanied by hydrogen loss or back transfer so as to produce even electron negative or positive fragment ions. The relative occurrence of the two fragmentation processes appears to vary according to the functional group in the aglycon which is bonded to glucuronic acid." @default.
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- W2081719565 date "1983-01-01" @default.
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- W2081719565 title "Analysis of glucuronides by fast atom bombardment" @default.
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- W2081719565 doi "https://doi.org/10.1016/0020-7381(83)80139-9" @default.
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