FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2081750595> ?p ?o ?g. }

• W2081750595 endingPage "4031" @default.
• W2081750595 startingPage "4023" @default.
• W2081750595 abstract "The N4O3 coordinating heptadentate ligand afforded binuclear complex [Cu2(H2L)(μ-OH)](ClO4)2 (1) and [Cu2(L)(H2O)2]PF6 (2). In complex 1, two copper ions are held together by μ-phenoxo and μ-hydroxo bridges, whereas in complex 2, the copper centers are connected only by a μ-phenoxo bridge. In 1, both the Cu(II) centers have square pyramidal geometry (τ = 0.01−0.205), whereas in the case of 2, one Cu(II) center has square pyramidal (τ = 0.2517) and other one has square based pyramidal distorted trigonal bipyramidal (τ = 0.54) geometry. Complexes 1 and 2 show an strong intramolecular and very weak antiferromagnetic interaction, respectively. Density-functional theory calculations were performed to establish the magneto structural correlation between the two paramagnetic copper(II) centers. Both of the complexes display a couple of one-electron reductive responses near −0.80 and −1.10 V. The complexes show significant catalytic activity at pH 8.5 on the oxidation of 3,5-di-tert-butylcatechol (3,5-DTBC) to 3,5-di-tert-butylquinone (3,5-DTBQ), and the activity measured in terms of kcat = 29−37 h−1." @default.
• W2081750595 created "2016-06-24" @default.
• W2081750595 creator A5030295049 @default.
• W2081750595 creator A5031213061 @default.
• W2081750595 creator A5044497796 @default.
• W2081750595 creator A5055445932 @default.
• W2081750595 creator A5079780490 @default.
• W2081750595 date "2008-04-16" @default.
• W2081750595 modified "2023-10-12" @default.
• W2081750595 title "Binuclear Copper(II) Complexes with N₄O₃ Coordinating Heptadentate Ligand: Synthesis, Structure, Magnetic Properties, Density-Functional Theory Study, and Catecholase Activity" @default.
• W2081750595 cites W1602639107 @default.
• W2081750595 cites W1965249399 @default.
• W2081750595 cites W1966824945 @default.
• W2081750595 cites W1967702070 @default.
• W2081750595 cites W1968074861 @default.
• W2081750595 cites W1968217392 @default.
• W2081750595 cites W1969305102 @default.
• W2081750595 cites W1970896157 @default.
• W2081750595 cites W1971858298 @default.
• W2081750595 cites W1977834467 @default.
• W2081750595 cites W1977925490 @default.
• W2081750595 cites W1979143818 @default.
• W2081750595 cites W1981373094 @default.
• W2081750595 cites W1986684351 @default.
• W2081750595 cites W1992111563 @default.
• W2081750595 cites W1993461718 @default.
• W2081750595 cites W1995287303 @default.
• W2081750595 cites W2003221148 @default.
• W2081750595 cites W2003262187 @default.
• W2081750595 cites W2008553568 @default.
• W2081750595 cites W2008584788 @default.
• W2081750595 cites W2013862228 @default.
• W2081750595 cites W2017884184 @default.
• W2081750595 cites W2018763502 @default.
• W2081750595 cites W2019347060 @default.
• W2081750595 cites W2023271753 @default.
• W2081750595 cites W2027333770 @default.
• W2081750595 cites W2028139723 @default.
• W2081750595 cites W2028291957 @default.
• W2081750595 cites W2034035406 @default.
• W2081750595 cites W2037328368 @default.
• W2081750595 cites W2038189735 @default.
• W2081750595 cites W2041041109 @default.
• W2081750595 cites W2045380708 @default.
• W2081750595 cites W2045952721 @default.
• W2081750595 cites W2046779204 @default.
• W2081750595 cites W2046946630 @default.
• W2081750595 cites W2047451626 @default.
• W2081750595 cites W2048645097 @default.
• W2081750595 cites W2049597257 @default.
• W2081750595 cites W2051331283 @default.
• W2081750595 cites W2058210956 @default.
• W2081750595 cites W2059290636 @default.
• W2081750595 cites W2060653314 @default.
• W2081750595 cites W2061356043 @default.
• W2081750595 cites W2067158830 @default.
• W2081750595 cites W2070413763 @default.
• W2081750595 cites W2070910778 @default.
• W2081750595 cites W2073647944 @default.
• W2081750595 cites W2077039404 @default.
• W2081750595 cites W2078146328 @default.
• W2081750595 cites W2080828521 @default.
• W2081750595 cites W2082125821 @default.
• W2081750595 cites W2082767443 @default.
• W2081750595 cites W2083819209 @default.
• W2081750595 cites W2086693343 @default.
• W2081750595 cites W2087013994 @default.
• W2081750595 cites W2087042268 @default.
• W2081750595 cites W2090155847 @default.
• W2081750595 cites W2093001905 @default.
• W2081750595 cites W2102455520 @default.
• W2081750595 cites W2115550277 @default.
• W2081750595 cites W2122793879 @default.
• W2081750595 cites W2143981217 @default.
• W2081750595 cites W2167531478 @default.
• W2081750595 cites W2319628733 @default.
• W2081750595 cites W2478789085 @default.
• W2081750595 cites W2951010535 @default.
• W2081750595 cites W4253803510 @default.
• W2081750595 doi "https://doi.org/10.1021/ic7015935" @default.
• W2081750595 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18412334" @default.
• W2081750595 hasPublicationYear "2008" @default.
• W2081750595 type Work @default.
• W2081750595 sameAs 2081750595 @default.
• W2081750595 citedByCount "103" @default.
• W2081750595 countsByYear W20817505952012 @default.
• W2081750595 countsByYear W20817505952013 @default.
• W2081750595 countsByYear W20817505952014 @default.
• W2081750595 countsByYear W20817505952015 @default.
• W2081750595 countsByYear W20817505952016 @default.
• W2081750595 countsByYear W20817505952017 @default.
• W2081750595 countsByYear W20817505952018 @default.
• W2081750595 countsByYear W20817505952019 @default.
• W2081750595 countsByYear W20817505952020 @default.
• W2081750595 countsByYear W20817505952021 @default.
• W2081750595 countsByYear W20817505952022 @default.
• W2081750595 countsByYear W20817505952023 @default.
• W2081750595 crossrefType "journal-article" @default.

• next