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- W2081767876 abstract "The coupled 1H and 13C nuclear magnetic relaxation in dichloromethane has been studied in acetone and deuterated acetone. The dynamical parameters have been found to be the same in the two media (Dxx = 4·1 × 10-10, Dyy = 2·0 × 10-10 Dzz = 8·6 × 10-10 s-1). The ratio of the random field spectral densities in the two solvents is lower than the theoretical value. This discrepancy has been ascribed to the different internal dynamics of the CD3 and CH3 groups. The isotopic content of the medium is shown to affect the relaxation times of the proton as well as the carbon nuclei." @default.
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- W2081767876 date "1985-02-10" @default.
- W2081767876 modified "2023-09-27" @default.
- W2081767876 title "Effect of solvent isotopic labelling on proton and carbon-13 longitudinal relaxation" @default.
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- W2081767876 doi "https://doi.org/10.1080/00268978500100231" @default.
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