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- W2081834259 abstract "Abstract Methyl 9(10)‐formylstearate from hydroformylated oleate is autoxidized effectively to the corresponding carboxystearate in the presence of metal naphthenates at 20 C. Up to 95% conversion is obtained by treatment with Ca naphthenate for 24 hr. Catalyst activity based on disappearance of formylstearate approximates the following order: Co>Pb>Mn>Ce>Fe>Zr>Ca. Decreasing yields of carboxyester obtained with different catalysts follow the approximate order: Ca>Pb≈Fe≈Zr≈Mn>Co>Ce. The active redox metal catalysts such as Co, Ce and Mn produce varying amounts of methyl stearate, epoxy‐, keto‐ and hydroxystearate as side products. Ca naphthenate minimizes free radical decarbonylation and other side reactions. Mechanisms are proposed for the formation of side products." @default.
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- W2081834259 date "1972-01-01" @default.
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- W2081834259 title "Methyl 9(10)-carboxystearate by catalytic oxidation of hydroformylated oleate" @default.
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- W2081834259 doi "https://doi.org/10.1007/bf02545144" @default.
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