Matches in SemOpenAlex for { <https://semopenalex.org/work/W2081850605> ?p ?o ?g. }
- W2081850605 endingPage "5363" @default.
- W2081850605 startingPage "5353" @default.
- W2081850605 abstract "Abstract The photochemical solvolyses of naphthalen‐1‐yl(phenyl)iodonium tetrafluoroborate and naphthalen‐2‐yl(phenyl)iodonium tetrafluoroborate in methanol regiospecifically yield the naphthalen‐1‐ and ‐2‐yl ethers but afford scrambled 1‐ and 2‐phenylnaphthalene Friedel–Crafts products. It is demonstrated that singlet naphthyl cations account for the formation of the naphthyl ethers, but that the cine substitution is most likely to be due to the intermediacy of triplet naphthyl cations. According to the experiments reported here, the singlet naphthyl cations are lower in energy than their triplet isomers. High‐level MO calculations for the cations in methanol support this finding. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)" @default.
- W2081850605 created "2016-06-24" @default.
- W2081850605 creator A5023429490 @default.
- W2081850605 creator A5036915262 @default.
- W2081850605 creator A5055120115 @default.
- W2081850605 creator A5058533738 @default.
- W2081850605 creator A5064912852 @default.
- W2081850605 date "2007-10-23" @default.
- W2081850605 modified "2023-09-30" @default.
- W2081850605 title "Photochemical Generation and Reactivity of Naphthyl Cations: <i>cine</i> Substitution" @default.
- W2081850605 cites W1523678163 @default.
- W2081850605 cites W1621007234 @default.
- W2081850605 cites W1973141166 @default.
- W2081850605 cites W1980123376 @default.
- W2081850605 cites W1983754380 @default.
- W2081850605 cites W1987335034 @default.
- W2081850605 cites W1987577139 @default.
- W2081850605 cites W1988017516 @default.
- W2081850605 cites W1990442032 @default.
- W2081850605 cites W1991609642 @default.
- W2081850605 cites W1992151592 @default.
- W2081850605 cites W1994033475 @default.
- W2081850605 cites W1994046947 @default.
- W2081850605 cites W1998247782 @default.
- W2081850605 cites W1999044658 @default.
- W2081850605 cites W2000417530 @default.
- W2081850605 cites W2002510197 @default.
- W2081850605 cites W2003262988 @default.
- W2081850605 cites W2004931973 @default.
- W2081850605 cites W2005210658 @default.
- W2081850605 cites W2009240161 @default.
- W2081850605 cites W2011534631 @default.
- W2081850605 cites W2014679160 @default.
- W2081850605 cites W2015200486 @default.
- W2081850605 cites W2020602095 @default.
- W2081850605 cites W2028098137 @default.
- W2081850605 cites W2038014804 @default.
- W2081850605 cites W2040783976 @default.
- W2081850605 cites W2045790390 @default.
- W2081850605 cites W2046581542 @default.
- W2081850605 cites W2047475259 @default.
- W2081850605 cites W2050378782 @default.
- W2081850605 cites W2052480851 @default.
- W2081850605 cites W2056576825 @default.
- W2081850605 cites W2057928587 @default.
- W2081850605 cites W2059464644 @default.
- W2081850605 cites W2065617724 @default.
- W2081850605 cites W2070173644 @default.
- W2081850605 cites W2079337007 @default.
- W2081850605 cites W2084149696 @default.
- W2081850605 cites W2090509055 @default.
- W2081850605 cites W2102328384 @default.
- W2081850605 cites W2104662659 @default.
- W2081850605 cites W2118074066 @default.
- W2081850605 cites W2118561314 @default.
- W2081850605 cites W2130623623 @default.
- W2081850605 cites W2133550406 @default.
- W2081850605 cites W2148284063 @default.
- W2081850605 cites W2149831457 @default.
- W2081850605 cites W2161744203 @default.
- W2081850605 cites W2164061561 @default.
- W2081850605 cites W2318059012 @default.
- W2081850605 cites W2329771502 @default.
- W2081850605 cites W2563550532 @default.
- W2081850605 cites W2950755847 @default.
- W2081850605 cites W2951214286 @default.
- W2081850605 cites W2952060850 @default.
- W2081850605 cites W4211246220 @default.
- W2081850605 cites W4239396415 @default.
- W2081850605 doi "https://doi.org/10.1002/ejoc.200700338" @default.
- W2081850605 hasPublicationYear "2007" @default.
- W2081850605 type Work @default.
- W2081850605 sameAs 2081850605 @default.
- W2081850605 citedByCount "18" @default.
- W2081850605 countsByYear W20818506052012 @default.
- W2081850605 countsByYear W20818506052013 @default.
- W2081850605 countsByYear W20818506052019 @default.
- W2081850605 countsByYear W20818506052020 @default.
- W2081850605 countsByYear W20818506052021 @default.
- W2081850605 crossrefType "journal-article" @default.
- W2081850605 hasAuthorship W2081850605A5023429490 @default.
- W2081850605 hasAuthorship W2081850605A5036915262 @default.
- W2081850605 hasAuthorship W2081850605A5055120115 @default.
- W2081850605 hasAuthorship W2081850605A5058533738 @default.
- W2081850605 hasAuthorship W2081850605A5064912852 @default.
- W2081850605 hasConcept C111185830 @default.
- W2081850605 hasConcept C121332964 @default.
- W2081850605 hasConcept C134121241 @default.
- W2081850605 hasConcept C142724271 @default.
- W2081850605 hasConcept C154881586 @default.
- W2081850605 hasConcept C155647269 @default.
- W2081850605 hasConcept C161790260 @default.
- W2081850605 hasConcept C178790620 @default.
- W2081850605 hasConcept C181500209 @default.
- W2081850605 hasConcept C185544564 @default.
- W2081850605 hasConcept C185592680 @default.
- W2081850605 hasConcept C191897082 @default.
- W2081850605 hasConcept C192562407 @default.